Pdf an industrial steam methane reformer optimization. An industrial steam methane reformer optimization using response surface methodology article pdf available in journal of natural gas science and engineering 36. The mixture of steam and gas enters the primary reformer natural gas fired primary reformer and oil fired primary reformer tubes, which are filled with a nickelbased reforming catalyst. Us6818028b2 steammethane reformer furnace with convection. Equilibrium composition out of a steam reformer at 26 bar with a feed steam to methane ratio of 2. The second is the steam methane reformer, which converts feedstock and steam to syngas mainly hydrogen and carbon monoxide at high temperature and moderate pressure. Methane steam reforming is a chemical process to produce hydrogen and synthesis gas mixture by combination of steam and methane in a reformer at appropriate temperature and pressure in presence of suitable metalbased catalysts 4. Redefining steam methane reformer performance in hydrogen.
This process contains two chemical reactions which ultimately convert water and methane usually in the form of. Methane steam reforming an overview sciencedirect topics. In smr, methane reacts with steam under 325 bar pressure 1 bar 14. Steam methane reforming smr is a chemical process used in the gas manufacturing industry to produce hydrogen on a large scale. The prereformer comprises catalystfilled tubes disposed in the transition section between the radiant and convection sections. The calculated effluent composition of a reformer always needs to be checked against the equilibrium constant equations to ensure that simulations agree with known values.
The feed material can be natural gas, liquid gas or naphta. Steam methane reforming hydrogen production air liquide. On the catalytic aspects of steammethane reforming a literature. The reactions for the two simultaneous smr mechanisms are shown as equations 1 and 2. With the help of the heat balance equation, it was established that the resulting transformation of substances in the steam methane reformer can be presented as a sequential heating of feed streams of methane and steam from the inlet temperature t 1 to the outlet temperature t 2, heat for smr reaction at the temperature t 2, and heat for. Under these conditions, the catalyst presents the average h2co. Life cycle assessment of hydrogen production via natural. The steam methane reforming smr process is the most widespread method to generate hydrogenrich synthesis gas from light carbohydrates. Figure 1 combined hydrogen production potential from biomass, wind and solar top and current hydrogen production from natural gas using steammethane reforming smr and potential hydrogen production from coal bottom. Us10384183b2 steam methane reformer tube outlet assembly.
They are converted endothermically with steam into synthesis gas in catalytic tube reactors. Steam methane reforming simulation hydrogen production. Hydrogen production by steam reforming chemical engineering. Here, steam reacts with methane to yield carbon monoxide and h 2 g at high temperature. We have chosen economically beneficial steam reforming of natural gas for hydrogen production. Steam methane reformer an overview sciencedirect topics. Optimization of the reformer with the waste heat recovery section can be tailored to suit multiple design cases for varying feed stock, fuels, and steam requirements.
The steam reformer represents the core operating unit of most large scale hydrogen production facilities. Steam methane reforming smr for hydrogen production. Steam methane reforming is the most common and economical way to make hydrogen. Lca is a systematic analytical method that helps identify and evaluate the environmental impacts of a specific process or competing processes. Pdf cfd simulation of a methane steam reforming reactor. May 01, 2010 product gas from the steam reforming of the methane and naphtha contains equilibrium amounts of hydrogen, carbon dioxide, carbon monoxide and excess steam. The equilibrium composition out of the steam reformer is shown in fig. The syngas stream contains h 2, co, co 2, and unconverted ch 4 and process steam. Figure 1 combined hydrogen production potential from biomass, wind and solar top and current hydrogen production from natural gas using steam methane reforming smr and potential hydrogen production from coal bottom. Waste heat recovery from flue gas and process gas is an important aspect of linde engineerings overall reformer design.
Methane steam reforming reaction behaviour in a packed. For decades, downfired steam methane reformer furnaces have utilized flue gas tunnels coffins along the radiant section floor to collect and improve flue gas flow uniformity. Methane steam reforming reaction behaviour in a packed bed. Hydrogen from natural gas via steam methane reforming smr. Product gas from the steam reforming of the methane and naphtha contains equilibrium amounts of hydrogen, carbon dioxide, carbon monoxide and excess steam. Hydrogen production via steam reforming with co2 capture. This name is commonly retained even when other feedstocks e. Steammethane reforming smr for hydrogen production. Pdf on the modeling of steam methane reforming researchgate. Osha cites corpus christi steam methane reformer plant for willful, serious violations for safety failures that exposed workers to health dangers.
Pdf benchscale steam reforming of methane for hydrogen. It is reversible and strongly endothermic, and according to the principle of le chatelier it must be carried out at high. The syngas from the reformer further goes through a water gas shift reactor where co and steam react to form h 2 and co 2. Design of process plant for producing hydrogen from steam. An industrial steam methane reformer optimization using response surface methodology article pdf available in journal of natural gas science and engineering 36 october 2016 with 3,601 reads.
Pdf modeling and simulations of steam methane reforming smr process to produce hydrogen and or syngas are presented in this article. This model predicts the reforming process for a variety of feed stocks and reformer con. The gasand steam mixture travels down into reformer tubes that hang in vertical rows surrounded by gas burners that heat the mixture. Proceedings of the 4th international gas processing symposium, 2015. Novel reformer technologies such as sorbent enhanced. For this purpose, methane was used the starting point and building block for the progressive understanding of reforming of complex hydrocarbons. Water enters the furnace, producing steam at a very high temperature. The steam methane reforming process can be broken down into five distinct steps. Co are also active for the methane steam reforming 25. Major process steps consist of sulfur removal, reforming, watergas shift wgs, and h2 product purification. Using a steam methane reformer smr, methane reacts with steam under 325 bar of pressure in the presence of a catalyst to produce hydrogen, carbon monoxide, and a. Xiao feng, in computer aided chemical engineering, 2018. The steam reforming plant consists of four basic sections bressan et al.
Steam methane reforming is the most widely used process for the generation of hydrogen. Chapter 5 describes some applications of methane reforming other than the conventional steam reforming. These onsite units provide a compact, efficient, and flexible alternative to other hydrogen supply schemes. The first is feedstock treatment where sulphur and other contaminants are removed. Steam methane reformer furnace with convectionheated pre reformer. Services the reformer process design is performed with a proprietary incremental kinetic model, and re. The prereformer tubes are transverse to the flow of flue gas from the radiant section. The design of the steam reforming process is in part dictated by these constraints. Thermodynamic equilibrium analysis of steam methane. Review of small stationary reformers for hydrogen production. Pdf an industrial steam methane reformer optimization using. Nrel award aco544027, equipment design and cost estimation for small modular biomass systems, synthesis gas cleanup and oxygen separation equipment. Therefore, steam reformer furnace combustion safety is fundamental to the overall safe operation of these large scale hydrogen plants.
Meanwhile, the steam methane reformer refers only to the fired chemical reactor in which reaction takes place. Osha cites corpus christi steam methane reformer plant for. Steam methane reforming is the most widely used process for bulk gas production, accounting for 95% of the hydrogen produced in the united states. Kinetics, catalysis and mechanism of methane steam reforming. Economic analysis of hydrogen production from steam reforming. Then, in chapter 4, catalyst deactivation is discussed. The primary reformer is a heat exchanger its function is to heat up process gas catalyst and reaction in the tubes combustion on the shell side dominant heat transfer by radiation. Process heat as well as flue gases are used for the. Due to its maturity, high efficiency, and relatively low cost, steam reforming is considered a viable option for supporting a future hydrogen economy.
The primary reformer operates at 40 bar and three discrete temperatures 800 c, 850 c, and 900 c. The methane steam reforming was studied by 26 in a fixed bed tubular quartz micro reactor with cobalt catalyst. Thermodynamic equilibrium analysis of steam methane reforming. Kinetics study and modelling of steam methane reforming. Steam methane reforming is a widelyused process to convert methane into a mixture of hydrogen and carbon monoxide syngas. Steam methane reforming simulation hydrogen production hysys tutorial p sims. The reformation chemistry occurs in a porous catalytic bed where energy is supplied through heating tubes to drive the endothermal. In fuel cell power generators, a steam reformer unit typically produces the hydrogen needed for the cell stack. The effect of the steammethane ratio on the methane conversion is shown in figure 1b. Hydroprime plants offer many advantages over traditional supply modes such as electrolytic plants, conventional steam methane plants and truckdelivered bulk hydrogen. The equilibrium curve intersects this line in a point whose position depends on the system temperature and pressure fig. Methane steam reforming is a wellestablished process as shown in fig. These include steam methane reforming smr, partial oxidation pox, autothermal reforming atr, methanol reforming, ammonia cracking and catalytic cracking of methane. Submitted to the school of graduate studies in partial fulfillment of the requirements for the degree of.
The prereformer achieves 1020% of the total reforming load, and can be. Comparison of catalyst geometries for methane steam. The conventional steam methane reformer consists of a furnace that contains tubes in it, with catalyst loaded in these tubes to speed up the rate of the reaction r1 21. Simple, robust control required no more complex than an industrial refrigeration. The startup and shutdown of the reformer can create transitional periods of in. Both reforming routes are governed by the steam reforming and watergas shift reactions shown in eqs. This is largely due to its cost effectivness in obtaining a high level of purity in its produced hydrogen. Reforming temperature profile low for steam raising.
Novel reformer technologies such as sorbent enhanced reforming, ion transport membranes, and plasma reformers are discussed. The catalyst showed stability and activity at a feed molar ratio sc21, wf 0. Steam methane reforming smr and autothermal reformer atr are two industrial examples of the primary and secondary reformers, respectively. The reformer tubes are full of nickel catalyst, which triggers a reaction, causing the methane in natural gas to react with water vapor to form hydrogen, carbon monoxide, and carbon dioxide. In the steam reforming process, a desulfurized hydrocarbon feedstock natural gas, refinery offgas, liquefied petroleum gas or naphtha is preheated, mixed with steam and optionally prereformed before passing a catalyst in a proprietary topfired steam reformer to produce hydrogen, carbon monoxide co and carbon dioxide co 2. Equipment design and cost estimation for small modular. The gasandsteam mixture travels down into reformer tubes that hang in vertical rows surrounded by gas burners that heat the mixture. In the reforming reaction, natural gas is mixed with steam, heated to over 1,500 degrees fahrenheit, and reacted with nickel catalyst to produce hydrogen h. The desulfurized hydrocarbon feed is mixed with superheated process steam in accordance with the steamcarbon relationship necessary for the reforming process. The present invention relates a steam methane reformer tube outlet assembly and a method of assembling or retrofitting same. A life cycle assessment lca of hydrogen production via natural gas steam reforming was performed to examine the net emissions of greenhouse gases, as well as other major environmental consequences. A steamhydrocarbon reformer employing a convectionheated prereformer is disclosed. Onsite hydrogen generation by steam methane reforming. The steammethane reforming smr process figure 3 reacts a hydrocarbon with steam h2o over a nickelbased catalyst to produce a mixture of hydrogen h2 and carbon monoxide co, generically known as synthesis gas syngas.
Kinetics providing detailed information of elementary reaction steps for this system, namely microkinetics, has not yet been fully addressed. The primary reformer is a typical steam methane reformer, and the secondary reformer is an autothermal reformer. Syngas production in what is called steam methane reforming, hightemperature steam 700c1,000c is used to produce raw syngas from a methane source, typically natural gas. Life cycle assessment of hydrogen production via natural gas. It involves the diffusion of reactants through bulk of gases to the surface of the catalyst particles and within the porous particles. Steam and hydrocarbon enter the reactor as feedstock, and hydrogen and carbon dioxide are generated at the end of the process. Pdf steam methane reforming is an endothermic reaction which is considered as one of the main processes in hydrogen and syngas. On the other hand, the process of combined reforming utilizes both of primary and secondary tools for production of synthesis gas, as it is commonly practiced in ammonia manufacturing. Pdf basic design of tubular steam reformer chathura. To minimize the methane content in the synthesis gas while simultaneously maximizing the h2 yield and preventing the formation of elemental carbon and keeping it from getting deposited on the catalyst, the reformer is operated with a higher steam carbon relationship than theoretically necessary. Environmental considerations and more demand for energy have been instigating the. This example illustrates the modeling of a steam reformer. In the overall steam methane reforming smr reaction, methane reacts with steam at high temperatures and moderate pressures in catalystfilled tubes to generate synthesis gas, a mixture of hydrogen, carbon monoxide and some carbon dioxide. These include steam methane reforming smr, partial oxidation pox, autothermal reforming atr, methanol reforming, ammonia cracking and catalytic.
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